Spin dynamics and zero-field splitting constants of the triplet exciplex generated by photoinduced electron transfer reaction between erythrosin B and duroquinone

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Spin dynamics and zero-field splitting constants of the triplet exciplex generated by photoinduced electron transfer reaction between erythrosin B and duroquinone

The spin dynamics of the duroquinone anion radical generated by photoinduced electron transfer reactions from triplet erythrosin B to duroquinone has been studied by using transient absorption and pulsed FT-EPR spectroscopy. Triplet exciplex formation as the reaction intermediate is verified by the observation of spin–orbit coupling induced electron spin polarization. The kinetic parameters for...

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ژورنال

عنوان ژورنال: Chemical Physics Letters

سال: 2002

ISSN: 0009-2614

DOI: 10.1016/s0009-2614(02)00804-7